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Caffeine's half-life averages 5–6 hours but ranges from 2–12 hours depending on genetics, liver function, smoking status, and pregnancy. After one half-life, 50% remains; after two, 25%; after three, 12.5%. To have less than 10% remaining at bedtime, your last cup should be 3 half-lives before sleep. Oral contraceptives roughly double the half-life.
Coffee ~95mg, Espresso ~63mg, Energy drink ~80-200mg
Caffeine remaining in your system
87 mg
44% of original dose